catena-Poly[cobalt(II)-di-μ-chlorido-κ4 Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ2 N 3:N 4]: an X-ray powder investigation
نویسندگان
چکیده
The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyl-tetra-zole ligand. The coordination polyhedra of both Co atoms adopt flattened octa-hedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetra-zole ring to form polymeric chains running along the a axis.
منابع مشابه
catena-Poly[[bis[1-(2-hydroxyethyl)-1H-tetrazole-κN 4]copper(II)]-di-μ-chlorido]: a powder study
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متن کاملA triclinic polymorph of catena-poly[[bis(N,N-dimethylformamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ4 N 1:N 5]
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009